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When it comes to quality assurance, what is the most important aspect of PPE related to compounding?

A appropriate hand washing

PPE stands for personal protective equipment and hand-washing is one of the easiest, yet most important, aspects of infection control. Always wash your hands prior to any compounding procedure or pharmacy process that involves direct contact with the drug product. This includes washing your hands prior to donning PPE in accordance with USP 795 and 797.